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Document 32019D2010

Commission Implementing Decision (EU) 2019/2010 of 12 November 2019 establishing the best available techniques (BAT) conclusions, under Directive 2010/75/EU of the European Parliament and of the Council, for waste incineration (notified under document C(2019) 7987) (Text with EEA relevance)

C/2019/7987

OJ L 312, 3.12.2019, p. 55–91 (BG, ES, CS, DA, DE, ET, EL, EN, FR, HR, IT, LV, LT, HU, MT, NL, PL, PT, RO, SK, SL, FI, SV)

Legal status of the document In force

ELI: http://data.europa.eu/eli/dec_impl/2019/2010/oj

3.12.2019   

EN

Official Journal of the European Union

L 312/55


COMMISSION IMPLEMENTING DECISION (EU) 2019/2010

of 12 November 2019

establishing the best available techniques (BAT) conclusions, under Directive 2010/75/EU of the European Parliament and of the Council, for waste incineration

(notified under document C(2019) 7987)

(Text with EEA relevance)

THE EUROPEAN COMMISSION,

Having regard to the Treaty on the Functioning of the European Union,

Having regard to Directive 2010/75/EU of the European Parliament and of the Council of 24 November 2010 on industrial emissions (integrated pollution prevention and control) (1), and in particular Article 13(5) thereof,

Whereas:

(1)

Best available techniques (BAT) conclusions are the reference for setting permit conditions for installations covered by Chapter II of Directive 2010/75/EU and competent authorities should set emission limit values which ensure that, under normal operating conditions, emissions do not exceed the emission levels associated with the best available techniques as laid down in the BAT conclusions.

(2)

The forum composed of representatives of Member States, the industries concerned and non-governmental organisations promoting environmental protection, established by Commission Decision of 16 May 2011 (2), provided the Commission on 27 February 2019 with its opinion on the proposed content of the BAT reference document for waste incineration. That opinion is publicly available.

(3)

The BAT conclusions set out in the Annex to this Decision are the key element of that BAT reference document.

(4)

The measures provided for in this Decision are in accordance with the opinion of the Committee established by Article 75(1) of Directive 2010/75/EU,

HAS ADOPTED THIS DECISION:

Article 1

The best available techniques (BAT) conclusions for waste incineration, as set out in the Annex, are adopted.

Article 2

This Decision is addressed to the Member States.

Done at Brussels, 12 November 2019.

For the Commission

Karmenu VELLA

Member of the Commission


(1)  OJ L 334, 17.12.2010, p. 17.

(2)  Commission Decision of 16 May 2011 establishing a forum for the exchange of information pursuant to Article 13 of Directive 2010/75/EU on industrial emissions (OJ C 146, 17.5.2011, p. 3).


ANNEX

BEST AVAILABLE TECHNIQUES (BAT) CONCLUSIONS FOR WASTE INCINERATION

SCOPE

These BAT conclusions concern the following activities specified in Annex I to Directive 2010/75/EU:

5.2.

Disposal or recovery of waste in waste incineration plants:

(a)

for non-hazardous waste with a capacity exceeding 3 tonnes per hour;

(b)

for hazardous waste with a capacity exceeding 10 tonnes per day.

5.2.

Disposal or recovery of waste in waste co-incineration plants:

(a)

for non-hazardous waste with a capacity exceeding 3 tonnes per hour;

(b)

for hazardous waste with a capacity exceeding 10 tonnes per day;

whose main purpose is not the production of material products and where at least one of the following conditions is fulfilled:

only waste, other than waste defined in Article 3(31)(b) of Directive 2010/75/EU, is combusted;

more than 40 % of the resulting heat release comes from hazardous waste;

mixed municipal waste is combusted.

5.3.

(a)

Disposal of non-hazardous waste with a capacity exceeding 50 tonnes per day involving the treatment of slags and/or bottom ashes from the incineration of waste.

5.3.

(b)

Recovery, or a mix of recovery and disposal, of non-hazardous waste with a capacity exceeding 75 tonnes per day involving the treatment of slags and/or bottom ashes from the incineration of waste.

5.1.

Disposal or recovery of hazardous waste with a capacity exceeding 10 tonnes per day involving the treatment of slags and/or bottom ashes from the incineration of waste.

These BAT conclusions do not address the following:

Pre-treatment of waste prior to incineration. This may be covered by the BAT conclusions for Waste Treatment (WT).

Treatment of incineration fly ashes and other residues resulting from flue-gas cleaning (FGC). This may be covered by the BAT conclusions for Waste Treatment (WT).

Incineration or co-incineration of exclusively gaseous waste, other than that resulting from the thermal treatment of waste.

Treatment of waste in plants covered by Article 42(2) of Directive 2010/75/EU.

Other BAT conclusions and reference documents which could be relevant for the activities covered by these BAT conclusions are the following:

Waste Treatment (WT);

Economics and Cross-Media Effects (ECM);

Emissions from Storage (EFS);

Energy Efficiency (ENE);

Industrial Cooling Systems (ICS);

Monitoring of Emissions to Air and Water from IED Installations (ROM);

Large Combustion Plants (LCP);

Common Waste Water and Waste Gas Treatment/Management Systems in the Chemical Sector (CWW).

DEFINITIONS

For the purposes of these BAT conclusions, the following general definitions apply:

Term

Definition

General terms

Boiler efficiency

Ratio between the energy produced at the boiler output (e.g. steam, hot water) and the waste’s and auxiliary fuel’s energy input to the furnace (as lower heating values).

Bottom ash treatment plant

Plant treating slags and/or bottom ashes from the incineration of waste in order to separate and recover the valuable fraction and to allow the beneficial use of the remaining fraction.

This does not include the sole separation of coarse metals at the incineration plant.

Clinical waste

Infectious or otherwise hazardous waste arising from healthcare institutions (e.g. hospitals).

Channelled emissions

Emissions of pollutants into the environment through any kind of duct, pipe, stack, chimney, funnel, flue, etc.

Continuous measurement

Measurement using an automated measuring system permanently installed on site.

Diffuse emissions

Non-channelled emissions (e.g. of dust, volatile compounds, odour) into the environment, which can result from ‘area’ sources (e.g. tankers) or ‘point’ sources (e.g. pipe flanges).

Existing plant

A plant that is not a new plant.

Fly ashes

Particles from the combustion chamber or formed within the flue-gas stream that are transported in the flue-gas.

Hazardous waste

Hazardous waste as defined in Article 3(2) of Directive 2008/98/EC of the European Parliament and of the Council (1).

Incineration of waste

The combustion of waste, either alone or in combination with fuels, in an incineration plant.

Incineration plant

Either a waste incineration plant as defined in Article 3(40) of Directive 2010/75/EU or a waste co-incineration plant as defined in Article 3(41) of Directive 2010/75/EU, covered by the scope of these BAT conclusions.

Major plant upgrade

A major change in the design or technology of a plant with major adjustments or replacements of the process and/or abatement technique(s) and associated equipment.

Municipal solid waste

Solid waste from households (mixed or separately collected) as well as solid waste from other sources that is comparable to household waste in nature and composition.

New plant

A plant first permitted following the publication of these BAT conclusions or a complete replacement of a plant following the publication of these BAT conclusions.

Other non-hazardous waste

Non-hazardous waste that is neither municipal solid waste nor sewage sludge.

Part of an incineration plant

For the purposes of determining the gross electrical efficiency or the gross energy efficiency of an incineration plant, a part of it may refer for example to:

an incineration line and its steam system in isolation;

a part of the steam system, connected to one or more boilers, routed to a condensing turbine;

the rest of the same steam system that is used for a different purpose, e.g. the steam is directly exported.

Periodic measurement

Measurement at specified time intervals using manual or automated methods.

Residues

Any liquid or solid waste which is generated by an incineration plant or by a bottom ash treatment plant.

Sensitive receptor

Area which needs special protection, such as:

residential areas;

areas where human activities are carried out (e.g. neighbouring workplaces, schools, daycare centres, recreational areas, hospitals or nursing homes).

Sewage sludge

Residual sludge from the storage, handling and treatment of domestic, urban or industrial waste water. For the purposes of these BAT conclusions, residual sludges constituting hazardous waste are excluded.

Slags and/or bottom ashes

Solid residues removed from the furnace once wastes have been incinerated.

Valid half-hourly average

A half-hourly average is considered valid when there is no maintenance or malfunction of the automated measuring system.


Term

Definition

Pollutants and parameters

As

The sum of arsenic and its compounds, expressed as As.

Cd

The sum of cadmium and its compounds, expressed as Cd.

Cd+Tl

The sum of cadmium, thallium and their compounds, expressed as Cd+Tl.

CO

Carbon monoxide.

Cr

The sum of chromium and its compounds, expressed as Cr.

Cu

The sum of copper and its compounds, expressed as Cu.

Dioxin-like PCBs

PCBs showing a similar toxicity to the 2,3,7,8-substituted PCDD/PCDF according to the World Health Organization (WHO).

Dust

Total particulate matter (in air).

HCl

Hydrogen chloride.

HF

Hydrogen fluoride.

Hg

The sum of mercury and its compounds, expressed as Hg.

Loss on ignition

Change in mass as a result of heating a sample under specified conditions.

N2O

Dinitrogen monoxide (nitrous oxide).

NH3

Ammonia.

NH4-N

Ammonium nitrogen, expressed as N, includes free ammonia (NH3) and ammonium (NH4 +).

Ni

The sum of nickel and its compounds, expressed as Ni.

NOX

The sum of nitrogen monoxide (NO) and nitrogen dioxide (NO2), expressed as NO2.

Pb

The sum of lead and its compounds, expressed as Pb.

PBDD/F

Polybrominated dibenzo-p-dioxins and –furans.

PCBs

Polychlorinated biphenyls.

PCDD/F

Polychlorinated dibenzo-p-dioxins and -furans.

POPs

Persistent Organic Pollutants as listed in Annex IV to Regulation (EC) No 850/2004 of the European Parliament and of the Council (2) and its amendments.

Sb

The sum of antimony and its compounds, expressed as Sb.

Sb+As+Pb+Cr+Co+Cu+Mn+Ni+V

The sum of antimony, arsenic, lead, chromium, cobalt, copper, manganese, nickel, vanadium and their compounds, expressed as Sb+As+Pb+Cr+Co+Cu+Mn+Ni+V.

SO2

Sulphur dioxide.

Sulphate (SO4 2-)

Dissolved sulphate, expressed as SO4 2-.

TOC

Total organic carbon, expressed as C (in water); includes all organic compounds.

TOC content (in solid residues)

Total organic carbon content. The quantity of carbon that is converted into carbon dioxide by combustion and which is not liberated as carbon dioxide by acid treatment.

TSS

Total suspended solids. Mass concentration of all suspended solids (in water), measured via filtration through glass fibre filters and gravimetry.

Tl

The sum of thallium and its compounds, expressed as Tl.

TVOC

Total volatile organic carbon, expressed as C (in air).

Zn

The sum of zinc and its compounds, expressed as Zn.

ACRONYMS

For the purposes of these BAT conclusions, the following acronyms apply:

Acronym

Definition

EMS

Environmental management system

FDBR

Fachverband Anlagenbau (from the previous name of the organisation: Fachverband Dampfkessel-, Behälter- und Rohrleitungsbau)

FGC

Flue-gas cleaning

OTNOC

Other than normal operating conditions

SCR

Selective catalytic reduction

SNCR

Selective non-catalytic reduction

I-TEQ

International toxic equivalent according to the North Atlantic Treaty Organization (NATO) schemes

WHO-TEQ

Toxic equivalent according to the World Health Organization (WHO) schemes

GENERAL CONSIDERATIONS

Best Available Techniques

The techniques listed and described in these BAT conclusions are neither prescriptive nor exhaustive. Other techniques may be used that ensure at least an equivalent level of environmental protection.

Unless otherwise stated, these BAT conclusions are generally applicable.

Emission levels associated with the best available techniques (BAT-AELs) for emissions to air

Emission levels associated with the best available techniques (BAT-AELs) for emissions to air given in these BAT conclusions refer to concentrations, expressed as mass of emitted substances per volume of flue-gas or of extracted air under the following standard conditions: dry gas at a temperature of 273,15 K and a pressure of 101,3 kPa, and expressed in mg/Nm3, µg/Nm3, ng I-TEQ/Nm3 or ng WHO-TEQ/Nm3.

The reference oxygen levels used to express BAT-AELs in this document are shown in the table below.

Activity

Reference oxygen level (OR)

Incineration of waste

11 dry vol-%

Bottom ash treatment

No correction for the oxygen level

The equation for calculating the emission concentration at the reference oxygen level is:

Image 1

Where:

ER

:

emission concentration at the reference oxygen level OR;

OR

:

reference oxygen level in vol-%;

EM

:

measured emission concentration;

OM

:

measured oxygen level in vol-%.

For averaging periods, the following definitions apply:

Type of measurement

Averaging period

Definition

Continuous

Half-hourly average

Average value over a period of 30 minutes

Daily average

Average over a period of one day based on valid half-hourly averages

Periodic

Average over the sampling period

Average value of three consecutive measurements of at least 30 minutes each (3)

Long-term sampling period

Value over a sampling period of 2 to 4 weeks

When waste is co-incinerated together with non-waste fuels, the BAT-AELs for emissions to air given in these BAT conclusions apply to the entire flue-gas volume generated.

Emission levels associated with the best available techniques (BAT-AELs) for emissions to water

Emission levels associated with the best available techniques (BAT-AELs) for emissions to water given in these BAT conclusions refer to concentrations (mass of emitted substances per volume of waste water), expressed in mg/l or ng I-TEQ/l.

For waste water from FGC, the BAT-AELs refer either to spot sampling (for TSS only) or to daily averages, i.e. 24-hour flow-proportional composite samples. Time-proportional composite sampling can be used provided that sufficient flow stability is demonstrated.

For waste water from bottom ash treatment, the BAT-AELs refer to either of the following two cases:

in the case of continuous discharges, daily average values, i.e. 24-hour flow-proportional composite samples;

in the case of batch discharges, average values over the release duration taken as flow-proportional composite samples, or, provided that the effluent is appropriately mixed and homogeneous, a spot sample taken before discharge.

The BAT-AELs for emissions to water apply at the point where the emission leaves the installation.

Energy efficiency levels associated with the best available techniques (BAT-AEELs)

The BAT-AEELs given in these BAT conclusions for the incineration of non-hazardous waste other than sewage sludge and of hazardous wood waste are expressed as:

gross electrical efficiency in the case of an incineration plant or part of an incineration plant that produces electricity using a condensing turbine;

gross energy efficiency in the case of an incineration plant or part of an incineration plant that:

produces only heat, or

produces electricity using a back-pressure turbine and heat with the steam leaving the turbine.

This is expressed as follows:

Gross electrical efficiency

Image 2

Gross energy efficiency

Image 3

Where:

— We

:

electrical power generated, in MW;

— Qhe

:

thermal power supplied to the heat exchangers on the primary side, in MW;

— Qde

:

directly exported thermal power (as steam or hot water) less the thermal power of the return flow, in MW;

— Qb

:

thermal power produced by the boiler, in MW;

— Qi

:

thermal power (as steam or hot water) that is used internally (e.g. for flue-gas reheating), in MW;

— Qth

:

thermal input to the thermal treatment units (e.g. furnaces), including the waste and auxiliary fuels that are used continuously (excluding for example for start-up), in MWth expressed as the lower heating value.

The BAT-AEELs given in these BAT conclusions for the incineration of sewage sludge and of hazardous waste other than hazardous wood waste are expressed as boiler efficiency.

BAT-AEELs are expressed as a percentage.

The monitoring associated with the BAT-AEELs is given in BAT 2.

Content of unburnt substances in bottom ashes/slags

The content of unburnt substances in the slags and/or bottom ashes is expressed as a percentage of the dry weight, either as the loss on ignition or as the TOC mass fraction.

1.   BAT CONCLUSIONS

1.1.   Environmental management systems

BAT 1. In order to improve the overall environmental performance, BAT is to elaborate and implement an environmental management system (EMS) that incorporates all of the following features:

(i)

commitment, leadership and accountability of the management, including senior management, for the implementation of an effective EMS;

(ii)

an analysis that includes the determination of the organisation’s context, the identification of the needs and expectations of interested parties, the identification of characteristics of the installation that are associated with possible risks for the environment (or human health) as well as of the applicable legal requirements relating to the environment;

(iii)

development of an environmental policy that includes the continuous improvement of the environmental performance of the installation;

(iv)

establishing objectives and performance indicators in relation to significant environmental aspects, including safeguarding compliance with applicable legal requirements;

(v)

planning and implementing the necessary procedures and actions (including corrective and preventive actions where needed), to achieve the environmental objectives and avoid environmental risks;

(vi)

determination of structures, roles and responsibilities in relation to environmental aspects and objectives and provision of the financial and human resources needed;

(vii)

ensuring the necessary competence and awareness of staff whose work may affect the environmental performance of the installation (e.g. by providing information and training);

(viii)

internal and external communication;

(ix)

fostering employee involvement in good environmental management practices;

(x)

establishing and maintaining a management manual and written procedures to control activities with significant environmental impact as well as relevant records;

(xi)

effective operational planning and process control;

(xii)

implementation of appropriate maintenance programmes;

(xiii)

emergency preparedness and response protocols, including the prevention and/or mitigation of the adverse (environmental) impacts of emergency situations;

(xiv)

when (re)designing a (new) installation or a part thereof, consideration of its environmental impacts throughout its life, which includes construction, maintenance, operation and decommissioning;

(xv)

implementation of a monitoring and measurement programme; if necessary, information can be found in the Reference Report on Monitoring of Emissions to Air and Water from IED Installations;

(xvi)

application of sectoral benchmarking on a regular basis;

(xvii)

periodic independent (as far as practicable) internal auditing and periodic independent external auditing in order to assess the environmental performance and to determine whether or not the EMS conforms to planned arrangements and has been properly implemented and maintained;

(xviii)

evaluation of causes of nonconformities, implementation of corrective actions in response to nonconformities, review of the effectiveness of corrective actions, and determination of whether similar nonconformities exist or could potentially occur;

(xix)

periodic review, by senior management, of the EMS and its continuing suitability, adequacy and effectiveness;

(xx)

following and taking into account the development of cleaner techniques.

Specifically for incineration plants and, where relevant, bottom ash treatment plants, BAT is also to incorporate the following features in the EMS:

(xxi)

for incineration plants, waste stream management (see BAT 9);

(xxii)

for bottom ash treatment plants, output quality management (see BAT 10);

(xxiii)

a residues management plan including measures aiming to:

(a)

minimise the generation of residues;

(b)

optimise the reuse, regeneration, recycling of, and/or energy recovery from the residues;

(c)

ensure the proper disposal of residues;

(xxiv)

for incineration plants, an OTNOC management plan (see BAT 18);

(xxv)

for incineration plants, an accident management plan (see Section 2.4);

(xxvi)

for bottom ash treatment plants, diffuse dust emissions management (see BAT 23);

(xxvii)

an odour management plan where an odour nuisance at sensitive receptors is expected and/or has been substantiated(see Section 2.4);

(xxviii)

a noise management plan (see also BAT 37) where a noise nuisance at sensitive receptors is expected and/or has been substantiated (see Section 2.4).

Note

Regulation (EC) No 1221/2009 establishes the European Union eco-management and audit scheme (EMAS), which is an example of an EMS consistent with this BAT.

Applicability

The level of detail and the degree of formalisation of the EMS will generally be related to the nature, scale and complexity of the installation, and the range of environmental impacts it may have (determined also by the type and the amount of waste processed).

1.2.   Monitoring

BAT 2.BAT is to determine either the gross electrical efficiency, the gross energy efficiency, or the boiler efficiency of the incineration plant as a whole or of all the relevant parts of the incineration plant.

Description

In the case of a new incineration plant or after each modification of an existing incineration plant that could significantly affect the energy efficiency, the gross electrical efficiency, the gross energy efficiency, or the boiler efficiency is determined by carrying out a performance test at full load.

In the case of an existing incineration plant that has not carried out a performance test, or where a performance test at full load cannot be carried out for technical reasons, the gross electrical efficiency, the gross energy efficiency, or the boiler efficiency can be determined taking into account the design values at performance test conditions.

For the performance test, no EN standard is available for the determination of the boiler efficiency of incineration plants. For grate-fired incineration plants, the FDBR guideline RL 7 may be used.

BAT 3. BAT is to monitor key process parameters relevant for emissions to air and water including those given below.

Stream/Location

Parameter(s)

Monitoring

Flue-gas from the incineration of waste

Flow, oxygen content, temperature, pressure, water vapour content

Continuous measurement

Combustion chamber

Temperature

Waste water from wet FGC

Flow, pH, temperature

Waste water from bottom ash treatment plants

Flow, pH, conductivity

BAT 4. BAT is to monitor channelled emissions to air with at least the frequency given below and in accordance with EN standards. If EN standards are not available, BAT is to use ISO, national or other international standards that ensure the provision of data of an equivalent scientific quality.

Substance/

Parameter

Process

Standard(s) (4)

Minimum monitoring frequency (5)

Monitoring associated with

NOX

Incineration of waste

Generic EN standards

Continuous

BAT 29

NH3

Incineration of waste when SNCR and/or SCR is used

Generic EN standards

Continuous

BAT 29

N2O

Incineration of waste in fluidised bed furnace

Incineration of waste when SNCR is operated with urea

EN 21258 (6)

Once every year

BAT 29

CO

Incineration of waste

Generic EN standards

Continuous

BAT 29

SO2

Incineration of waste

Generic EN standards

Continuous

BAT 27

HCl

Incineration of waste

Generic EN standards

Continuous

BAT 27

HF

Incineration of waste

Generic EN standards

Continuous (7)

BAT 27

Dust

Bottom ash treatment

EN 13284-1

Once every year

BAT 26

Incineration of waste

Generic EN standards and EN 13284-2

Continuous

BAT 25

Metals and metalloids except mercury (As, Cd, Co, Cr, Cu, Mn, Ni, Pb, Sb, Tl, V)

Incineration of waste

EN 14385

Once every six months

BAT 25

Hg

Incineration of waste

Generic EN standards and EN 14884

Continuous (8)

BAT 31

TVOC

Incineration of waste

Generic EN standards

Continuous

BAT 30

PBDD/F

Incineration of waste (9)

No EN standard available

Once every six months

BAT 30

PCDD/F

Incineration of waste

EN 1948-1, EN 1948-2, EN 1948-3

Once every six months for short-term sampling

BAT 30

No EN standard available for long-term sampling,

EN 1948-2, EN 1948-3

Once every month for long-term sampling (10)

BAT 30

Dioxin-like PCBs

Incineration of waste

EN 1948-1, EN 1948-2, EN 1948-4

Once every six months for short-term sampling (11)

BAT 30

No EN standard available for long-term sampling,

EN 1948-2, EN 1948-4

Once every month for long-term sampling  (10)  (11)

BAT 30

Benzo[a]pyrene

Incineration of waste

No EN standard available

Once every year

BAT 30

BAT 5. BAT is to appropriately monitor channelled emissions to air from the incineration plant during OTNOC.

Description

The monitoring can be carried out by direct emission measurements (e.g. for the pollutants that are monitored continuously) or by monitoring of surrogate parameters if this proves to be of equivalent or better scientific quality than direct emission measurements. Emissions during start-up and shutdown while no waste is being incinerated, including emissions of PCDD/F, are estimated based on measurement campaigns, e.g. every three years, carried out during planned start-up/shutdown operations.

BAT 6. BAT is to monitor emissions to water from FGC and/or bottom ash treatment with at least the frequency given below and in accordance with EN standards. If EN standards are not available, BAT is to use ISO, national or other international standards that ensure the provision of data of an equivalent scientific quality.

Substance/Parameter

Process

Standard(s)

Minimum monitoring frequency

Monitoring associated with

Total organic carbon (TOC)

FGC

EN 1484

Once every month

BAT 34

Bottom ash treatment

Once every month  (12)

Total suspended solids (TSS)

FGC

EN 872

Once every day  (13)

Bottom ash treatment

Once every month  (12)

As

FGC

Various EN standards available (e.g. EN ISO 11885, EN ISO 15586 or EN ISO 17294-2)

Once every month

Cd

FGC

Cr

FGC

Cu

FGC

Mo

FGC

Ni

FGC

Pb

FGC

Once every month

Bottom ash treatment

Once every month  (12)

Sb

FGC

Once every month

Tl

FGC

Zn

FGC

Hg

FGC

Various EN standards available (e.g. EN ISO 12846 or EN ISO 17852)

Ammonium-nitrogen (NH4-N)

Bottom ash treatment

Various EN standards available (e.g. EN ISO 11732, EN ISO 14911)

Once every month  (12)

Chloride (Cl-)

Bottom ash treatment

Various EN standards available (e.g. EN ISO 10304-1, EN ISO 15682)

Sulphate (SO4 2-)

Bottom ash treatment

EN ISO 10304-1

PCDD/F

FGC

No EN standard available

Once every month  (12)

Bottom ash treatment

Once every six months

BAT 7. BAT is to monitor the content of unburnt substances in slags and bottom ashes at the incineration plant with at least the frequency given below and in accordance with EN standards.

Parameter

Standard(s)

Minimum monitoring frequency

Monitoring associated with

Loss on ignition  (14)

EN 14899 and either EN 15169 or EN 15935

Once every three months

BAT 14

Total organic carbon  (14)  (15)

EN 14899 and either EN 13137 or EN 15936

BAT 8. For the incineration of hazardous waste containing POPs, BAT is to determine the POP content in the output streams (e.g. slags and bottom ashes, flue-gas, waste water) after the commissioning of the incineration plant and after each change that may significantly affect the POP content in the output streams.

Description

The POP content in the output streams is determined by direct measurements or by indirect methods (e.g. the cumulated quantity of POPs in the fly ashes, dry FGC residues, waste water from FGC and related waste water treatment sludge may be determined by monitoring the POP contents in the flue-gas before and after the FGC system) or based on studies representative of the plant.

Applicability

Only applicable for plants that:

incinerate hazardous waste with POP levels prior to incineration exceeding the concentration limits defined in Annex IV to Regulation (EC) No 850/2004 and amendments; and

do not meet the process description specifications of Chapter IV.G.2 point (g) of the UNEP technical guidelines UNEP/CHW.13/6/Add.1/Rev.1.

1.3.   General environmental and combustion performance

BAT 9. In order to improve the overall environmental performance of the incineration plant by waste stream management (see BAT 1), BAT is to use all of the techniques (a) to (c) given below, and, where relevant, also techniques (d), (e) and (f).

 

Technique

Description

(a)

Determination of the types of waste that can be incinerated

Based on the characteristics of the incineration plant, identification of the types of waste which can be incinerated in terms of, for example, the physical state, the chemical characteristics, the hazardous properties, and the acceptable ranges of calorific value, humidity, ash content and size.

(b)

Set-up and implementation of waste characterisation and pre-acceptance procedures

These procedures aim to ensure the technical (and legal) suitability of waste treatment operations for a particular waste prior to the arrival of the waste at the plant. They include procedures to collect information about the waste input and may include waste sampling and characterisation to achieve sufficient knowledge of the waste composition. Waste pre-acceptance procedures are risk-based considering, for example, the hazardous properties of the waste, the risks posed by the waste in terms of process safety, occupational safety and environmental impact, as well as the information provided by the previous waste holder(s).

(c)

Set-up and implementation of waste acceptance procedures

Acceptance procedures aim to confirm the characteristics of the waste, as identified at the pre-acceptance stage. These procedures define the elements to be verified upon the delivery of the waste at the plant as well as the waste acceptance and rejection criteria. They may include waste sampling, inspection and analysis. Waste acceptance procedures are risk-based considering, for example, the hazardous properties of the waste, the risks posed by the waste in terms of process safety, occupational safety and environmental impact, as well as the information provided by the previous waste holder(s). The elements to be monitored for each type of waste are detailed in BAT 11.

(d)

Set-up and implementation of a waste tracking system and inventory

A waste tracking system and inventory aims to track the location and quantity of waste in the plant. It holds all the information generated during waste pre-acceptance procedures (e.g. date of arrival at the plant and unique reference number of the waste, information on the previous waste holder(s), pre-acceptance and acceptance analysis results, nature and quantity of waste held on site including all identified hazards), acceptance, storage, treatment and/or transfer off site. The waste tracking system is risk-based considering, for example, the hazardous properties of the waste, the risks posed by the waste in terms of process safety, occupational safety and environmental impact, as well as the information provided by the previous waste holder(s).

The waste tracking system includes clear labelling of wastes that are stored in places other than the waste bunker or sludge storage tank (e.g. in containers, drums, bales or other forms of packaging) such that they can be identified at all times.

(e)

Waste segregation

Wastes are kept separated depending on their properties in order to enable easier and environmentally safer storage and incineration. Waste segregation relies on the physical separation of different wastes and on procedures that identify when and where wastes are stored.

(f)

Verification of waste compatibility prior to the mixing or blending of hazardous wastes

Compatibility is ensured by a set of verification measures and tests in order to detect any unwanted and/or potentially dangerous chemical reactions between wastes (e.g. polymerisation, gas evolution, exothermal reaction, decomposition) upon mixing or blending. The compatibility tests are risk-based considering, for example, the hazardous properties of the waste, the risks posed by the waste in terms of process safety, occupational safety and environmental impact, as well as the information provided by the previous waste holder(s).

BAT 10. In order to improve the overall environmental performance of the bottom ash treatment plant, BAT is to include output quality management features in the EMS (see BAT 1).

Description

Output quality management features are included in the EMS, so as to ensure that the output of the bottom ash treatment is in line with expectations, using existing EN standards where available. This also allows the performance of the bottom ash treatment to be monitored and optimised.

BAT 11. In order to improve the overall environmental performance of the incineration plant, BAT is to monitor the waste deliveries as part of the waste acceptance procedures (see BAT 9(c)) including, depending on the risk posed by the incoming waste, the elements given below.

Waste type

Waste delivery monitoring

Municipal solid waste and other non-hazardous waste

Radioactivity detection

Weighing of the waste deliveries

Visual inspection

Periodic sampling of waste deliveries and analysis of key properties/substances (e.g. calorific value, content of halogens and metals/metalloids). For municipal solid waste, this involves separate unloading.

Sewage sludge

Weighing of the waste deliveries (or measuring the flow if the sewage sludge is delivered via pipeline)

Visual inspection, as far as technically possible

Periodic sampling and analysis of key properties/substances (e.g. calorific value, content of water, ash and mercury)

Hazardous waste other than clinical waste

Radioactivity detection

Weighing of the waste deliveries

Visual inspection, as far as technically possible

Control and comparison of individual waste deliveries with the declaration of the waste producer

Sampling of the content of:

all bulk tankers and trailers

packed waste (e.g. in drums, intermediate bulk containers (IBCs) or smaller packaging)

and analysis of:

combustion parameters (including calorific value and flashpoint)

waste compatibility, to detect possible hazardous reactions upon blending or mixing of wastes, prior to storage (BAT 9 f)

key substances including POPs, halogens and sulphur, metals/metalloids

Clinical waste

Radioactivity detection

Weighing of the waste deliveries

Visual inspection of the packaging integrity

BAT 12. In order to reduce the environmental risks associated with the reception, handling and storage of waste, BAT is to use both of the techniques given below.

 

Technique

Description

(a)

Impermeable surfaces with an adequate drainage infrastructure

Depending on the risks posed by the waste in terms of soil or water contamination, the surface of the waste reception, handling and storage areas is made impermeable to the liquids concerned and fitted with an adequate drainage infrastructure (see BAT 32). The integrity of this surface is periodically verified, as far as technically possible.

(b)

Adequate waste storage capacity

Measures are taken to avoid accumulation of waste, such as:

the maximum waste storage capacity is clearly established and not exceeded, taking into account the characteristics of the wastes (e.g. regarding the risk of fire) and the treatment capacity;

the quantity of waste stored is regularly monitored against the maximum allowed storage capacity;

for wastes that are not mixed during storage (e.g. clinical waste, packed waste), the maximum residence time is clearly established.

BAT 13. In order to reduce the environmental risk associated with the storage and handling of clinical waste, BAT is to use a combination of the techniques given below.

 

Technique

Description

(a)

Automated or semi-automated waste handling

Clinical wastes are unloaded from the truck to the storage area using an automated or manual system depending on the risk posed by this operation. From the storage area the clinical wastes are fed into the furnace by an automated feeding system.

(b)

Incineration of non-reusable sealed containers, if used

Clinical waste is delivered in sealed and robust combustible containers that are never opened throughout storage and handling operations. If needles and sharps are disposed of in them, the containers are puncture-proof as well.

(c)

Cleaning and disinfection of reusable containers, if used

Reusable waste containers are cleaned in a designated cleaning area and disinfected in a facility specifically designed for disinfection. Any leftovers from the cleaning operations are incinerated.

BAT 14. In order to improve the overall environmental performance of the incineration of waste, to reduce the content of unburnt substances in slags and bottom ashes, and to reduce emissions to air from the incineration of waste, BAT is to use an appropriate combination of the techniques given below.

 

Technique

Description

Applicability

(a)

Waste blending and mixing

Waste blending and mixing prior to incineration includes for example the following operations:

bunker crane mixing;

using a feed equalisation system;

blending of compatible liquid and pasty wastes.

In some cases, solid wastes are shredded prior to mixing.

Not applicable where direct furnace feeding is required due to safety considerations or waste characteristics (e.g. infectious clinical waste, odorous wastes, or wastes that are prone to releasing volatile substances).

Not applicable where undesired reactions may occur between different types of waste (see BAT 9(f)).

(b)

Advanced control system

See Section 2.1

Generally applicable.

(c)

Optimisation of the incineration process

See Section 2.1

Optimisation of the design is not applicable to existing furnaces.


Table 1

BAT-associated environmental performance levels for unburnt substances in slags and bottom ashes from the incineration of waste

Parameter

Unit

BAT-AEPL

TOC content in slags and bottom ashes (16)

Dry wt-%

1–3 (17)

Loss on ignition of slags and bottom ashes (16)

Dry wt-%

1–5 (17)

The associated monitoring is in BAT 7.

BAT 15. In order to improve the overall environmental performance of the incineration plant and to reduce emissions to air, BAT is to set up and implement procedures for the adjustment of the plant’s settings, e.g. through the advanced control system (see description in Section 2.1), as and when needed and practicable, based on the characterisation and control of the waste (see BAT 11).

BAT 16. In order to improve the overall environmental performance of the incineration plant and to reduce emissions to air, BAT is to set up and implement operational procedures (e.g. organisation of the supply chain, continuous rather than batch operation) to limit as far as practicable shutdown and start-up operations.

BAT 17. In order to reduce emissions to air and, where relevant, to water from the incineration plant, BAT is to ensure that the FGC system and the waste water treatment plant are appropriately designed (e.g. considering the maximum flow rate and pollutant concentrations), operated within their design range, and maintained so as to ensure optimal availability.

BAT 18. In order to reduce the frequency of the occurrence of OTNOC and to reduce emissions to air and, where relevant, to water from the incineration plant during OTNOC, BAT is to set up and implement a risk-based OTNOC management plan as part of the environmental management system (see BAT 1) that includes all of the following elements:

identification of potential OTNOC (e.g. failure of equipment critical to the protection of the environment (‘critical equipment’)), of their root causes and of their potential consequences, and regular review and update of the list of identified OTNOC following the periodic assessment below;

appropriate design of critical equipment (e.g. compartmentalisation of the bag filter, techniques to heat up the flue-gas and obviate the need to bypass the bag filter during start-up and shutdown, etc.);

set-up and implementation of a preventive maintenance plan for critical equipment (see BAT 1(xii));

monitoring and recording of emissions during OTNOC and associated circumstances (see BAT 5);

periodic assessment of the emissions occurring during OTNOC (e.g. frequency of events, duration, amount of pollutants emitted) and implementation of corrective actions if necessary.

1.4.   Energy efficiency

BAT 19. In order to increase the resource efficiency of the incineration plant, BAT is to use a heat recovery boiler.

Description

The energy contained in the flue-gas is recovered in a heat recovery boiler producing hot water and/or steam, which may be exported, used internally, and/or used to produce electricity.

Applicability

In the case of plants dedicated to the incineration of hazardous waste, the applicability may be limited by:

the stickiness of the fly ashes;

the corrosiveness of the flue-gas.

BAT 20. In order to increase the energy efficiency of the incineration plant, BAT is to use an appropriate combination of the techniques given below.

 

Technique

Description

Applicability

(a)

Drying of sewage sludge

After mechanical dewatering, sewage sludge is further dried, using for example low-grade heat, before it is fed to the furnace.

The extent to which sludge can be dried depends on the furnace feeding system.

Applicable within the constraints associated with the availability of low-grade heat.

(b)

Reduction of the flue-gas flow

The flue-gas flow is reduced through, e.g.:

improving the primary and secondary combustion air distribution;

flue-gas recirculation (see Section 2.2).

A smaller flue-gas flow reduces the energy demand of the plant (e.g. for induced draught fans).

For existing plants, the applicability of flue-gas recirculation may be limited due to technical constraints (e.g. pollutant load in the flue-gas, incineration conditions).

(c)

Minimisation of heat losses

Heat losses are minimised through, e.g.:

use of integral furnace-boilers, allowing for heat to also be recovered from the furnace sides;

thermal insulation of furnaces and boilers;

flue-gas recirculation (see Section 2.2);

recovery of heat from the cooling of slags and bottom ashes (see BAT 20(i)).

Integral furnace-boilers are not applicable to rotary kilns or to other furnaces dedicated to the high-temperature incineration of hazardous waste.

(d)

Optimisation of the boiler design

The heat transfer in the boiler is improved by optimising, for example, the:

flue-gas velocity and distribution;

water/steam circulation;

convection bundles;

on-line and off-line boiler cleaning systems in order to minimise the fouling of the convection bundles.

Applicable to new plants and to major retrofits of existing plants.

(e)

Low-temperature flue-gas heat exchangers

Special corrosion-resistant heat exchangers are used to recover additional energy from the flue-gas at the boiler exit, after an ESP, or after a dry sorbent injection system.

Applicable within the constraints of the operating temperature profile of the FGC system.

In the case of existing plants, the applicability may be limited by a lack of space.

(f)

High steam conditions

The higher the steam conditions (temperature and pressure), the higher the electricity conversion efficiency allowed by the steam cycle.

Working at high steam conditions (e.g. above 45 bar, 400 °C) requires the use of special steel alloys or refractory cladding to protect the boiler sections that are exposed to the highest temperatures.

Applicable to new plants and to major retrofits of existing plants, where the plant is mainly oriented towards the generation of electricity.

The applicability may be limited by:

the stickiness of the fly ashes;

the corrosiveness of the flue-gas.

(g)

Cogeneration

Cogeneration of heat and electricity where the heat (mainly from the steam that leaves the turbine) is used for producing hot water/steam to be used in industrial processes/activities or in a district heating/cooling network.

Applicable within the constraints associated with the local heat and power demand and/or availability of networks.

(h)

Flue-gas condenser

A heat exchanger or a scrubber with a heat exchanger, where the water vapour contained in the flue-gas condenses, transferring the latent heat to water at a sufficiently low temperature (e.g. return flow of a district heating network).

The flue-gas condenser also provides co-benefits by reducing emissions to air (e.g. of dust and acid gases).

The use of heat pumps can increase the amount of energy recovered from flue-gas condensation.

Applicable within the constraints associated with the demand for low-temperature heat, e.g. by the availability of a district heating network with a sufficiently low return temperature.

(i)

Dry bottom ash handling

Dry, hot bottom ash falls from the grate onto a transport system and is cooled down by ambient air. Energy is recovered by using the cooling air for combustion.

Only applicable to grate furnaces.

There may be technical restrictions that prevent retrofitting to existing furnaces.


Table 2

BAT-associated energy efficiency levels (BAT-AEELs) for the incineration of waste

(%)

BAT-AEEL

Plant

Municipal solid waste, other non-hazardous waste and hazardous wood waste

Hazardous waste other than hazardous wood waste (18)

Sewage sludge

Gross electrical efficiency  (19)  (20)

Gross energy efficiency (21)

Boiler efficiency

New plant

25–35

72–91  (22)

60–80

60–70  (23)

Existing plant

20–35

The associated monitoring is in BAT 2.

1.5.   Emissions to air

1.5.1.   Diffuse emissions

BAT 21. In order to prevent or reduce diffuse emissions from the incineration plant, including odour emissions, BAT is to:

store solid and bulk pasty wastes that are odorous and/or prone to releasing volatile substances in enclosed buildings under controlled subatmospheric pressure and use the extracted air as combustion air for incineration or send it to another suitable abatement system in the case of a risk of explosion;

store liquid wastes in tanks under appropriate controlled pressure and duct the tank vents to the combustion air feed or to another suitable abatement system;

control the risk of odour during complete shutdown periods when no incineration capacity is available, e.g. by:

sending the vented or extracted air to an alternative abatement system, e.g. a wet scrubber, a fixed adsorption bed;

minimising the amount of waste in storage, e.g. by interrupting, reducing or transferring waste deliveries, as a part of waste stream management (see BAT 9);

storing waste in properly sealed bales.

BAT 22. In order to prevent diffuse emissions of volatile compounds from the handling of gaseous and liquid wastes that are odorous and/or prone to releasing volatile substances at incineration plants, BAT is to introduce them into the furnace by direct feeding.

Description

For gaseous and liquid wastes delivered in bulk waste containers (e.g. tankers), direct feeding is carried out by connecting the waste container to the furnace feeding line. The container is then emptied by pressurising it with nitrogen or, if the viscosity is low enough, by pumping the liquid.

For gaseous and liquid wastes delivered in waste containers suitable for incineration (e.g. drums), direct feeding is carried out by introducing the containers directly in the furnace.

Applicability

May not be applicable to the incineration of sewage sludge depending, for example, on the water content and on the need for pre-drying or mixing with other wastes.

BAT 23. In order to prevent or reduce diffuse dust emissions to air from the treatment of slags and bottom ashes, BAT is to include in the environmental management system (see BAT 1) the following diffuse dust emissions management features:

identification of the most relevant diffuse dust emission sources (e.g. using EN 15445);

definition and implementation of appropriate actions and techniques to prevent or reduce diffuse emissions over a given time frame.

BAT 24. In order to prevent or reduce diffuse dust emissions to air from the treatment of slags and bottom ashes, BAT is to use an appropriate combination of the techniques given below.

 

Technique

Description

Applicability

(a)

Enclose and cover equipment

Enclose/encapsulate potentially dusty operations (such as grinding, screening) and/or cover conveyors and elevators.

Enclosure can also be accomplished by installing all of the equipment in a closed building.

Installing the equipment in a closed building may not be applicable to mobile treatment devices.

(b)

Limit height of discharge

Match the discharge height to the varying height of the heap, automatically if possible (e.g. conveyor belts with adjustable heights).

Generally applicable.

(c)

Protect stockpiles against prevailing winds

Protect bulk storage areas or stockpiles with covers or wind barriers such as screening, walling or vertical greenery, as well as correctly orienting the stockpiles in relation to the prevailing wind.

Generally applicable.

(d)

Use water sprays

Install water spray systems at the main sources of diffuse dust emissions. The humidification of dust particles aids dust agglomeration and settling.

Diffuse dust emissions at stockpiles are reduced by ensuring appropriate humidification of the charging and discharging points, or of the stockpiles themselves.

Generally applicable.

(e)

Optimise moisture content

Optimise the moisture content of the slags/bottom ashes to the level required for efficient recovery of metals and mineral materials while minimising the dust release.

Generally applicable.

(f)

Operate under subatmospheric pressure

Carry out the treatment of slags and bottom ashes in enclosed equipment or buildings (see technique a) under subatmospheric pressure to enable treatment of the extracted air with an abatement technique (see BAT 26) as channelled emissions.

Only applicable to dry-discharged and other low-moisture bottom ashes.

1.5.2.   Channelled emissions

1.5.2.1.   Emissions of dust, metals and metalloids

BAT 25. In order to reduce channelled emissions to air of dust, metals and metalloids from the incineration of waste, BAT is to use one or a combination of the techniques given below.

 

Technique

Description

Applicability

(a)

Bag filter

See Section 2.2

Generally applicable to new plants.

Applicable to existing plants within the constraints associated with the operating temperature profile of the FGC system.

(b)

Electrostatic precipitator

See Section 2.2

Generally applicable.

(c)

Dry sorbent injection

See Section 2.2.

Not relevant for the reduction of dust emissions.

Adsorption of metals by injection of activated carbon or other reagents in combination with a dry sorbent injection system or a semi-wet absorber that is used to reduce acid gas emissions.

Generally applicable.

(d)

Wet scrubber

See Section 2.2.

Wet scrubbing systems are not used to remove the main dust load but, installed after other abatement techniques, to further reduce the concentrations of dust, metals and metalloids in the flue-gas.

There may be applicability restrictions due to low water availability, e.g. in arid areas.

(e)

Fixed- or moving-bed adsorption

See Section 2.2.

The system is used mainly to adsorb mercury and other metals and metalloids as well as organic compounds including PCDD/F, but also acts as an effective polishing filter for dust.

The applicability may be limited by the overall pressure drop associated with the FGC system configuration.

In the case of existing plants, the applicability may be limited by a lack of space.


Table 3

BAT-associated emission levels (BAT-AELs) for channelled emissions to air of dust, metals and metalloids from the incineration of waste

(mg/Nm3)

Parameter

BAT-AEL

Averaging period

Dust

< 2–5  (24)

Daily average

Cd+Tl

0,005–0,02

Average over the sampling period

Sb+As+Pb+Cr+Co+Cu+Mn+Ni+V

0,01–0,3

Average over the sampling period

The associated monitoring is in BAT 4.

BAT 26. In order to reduce channelled dust emissions to air from the enclosed treatment of slags and bottom ashes with extraction of air (see BAT 24(f)), BAT is to treat the extracted air with a bag filter (see Section 2.2).

Table 4

BAT-associated emission levels (BAT-AELs) for channelled dust emissions to air from the enclosed treatment of slags and bottom ashes with extraction of air

(mg/Nm3)

Parameter

BAT-AEL

Averaging period

Dust

2–5

Average over the sampling period

The associated monitoring is in BAT 4.

1.5.2.2.   Emissions of HCl, HF and SO2

BAT 27. In order to reduce channelled emissions of HCl, HF and SO2 to air from the incineration of waste, BAT is to use one or a combination of the techniques given below.

 

Technique

Description

Applicability

(a)

Wet scrubber

See Section 2.2

There may be applicability restrictions due to low water availability, e.g. in arid areas.

(b)

Semi-wet absorber

See Section 2.2

Generally applicable.

(c)

Dry sorbent injection

See Section 2.2

Generally applicable.

(d)

Direct desulphurisation

See Section 2.2.

Used for partial abatement of acid gas emissions upstream of other techniques.

Only applicable to fluidised bed furnaces.

(e)

Boiler sorbent injection

See Section 2.2.

Used for partial abatement of acid gas emissions upstream of other techniques.

Generally applicable.

BAT 28. In order to reduce channelled peak emissions of HCl, HF and SO2 to air from the incineration of waste while limiting the consumption of reagents and the amount of residues generated from dry sorbent injection and semi-wet absorbers, BAT is to use technique (a) or both of the techniques given below.

 

Technique

Description

Applicability

(a)

Optimised and automated reagent dosage

The use of continuous HCl and/or SO2 measurements (and/or of other parameters that may prove useful for this purpose) upstream and/or downstream of the FGC system for the optimisation of the automated reagent dosage.

Generally applicable.

(b)

Recirculation of reagents

The recirculation of a proportion of the collected FGC solids to reduce the amount of unreacted reagent(s) in the residues.

The technique is particularly relevant in the case of FGC techniques operating with a high stoichiometric excess.

Generally applicable to new plants.

Applicable to existing plants within the constraints of the size of the bag filter.


Table 5

BAT-associated emission levels (BAT-AELs) for channelled emissions to air of HCl, HF and SO2 from the incineration of waste

(mg/Nm3)

Parameter

BAT-AEL

Averaging period

New plant

Existing plant

HCl

< 2–6  (25)

< 2–8  (25)

Daily average

HF

< 1

< 1

Daily average or average over the sampling period

SO2

5–30

5–40

Daily average

The associated monitoring is in BAT 4.

1.5.2.3.   Emissions of NOX, N2O, CO and NH3

BAT 29. In order to reduce channelled NOX emissions to air while limiting the emissions of CO and N2O from the incineration of waste and the emissions of NH3 from the use of SNCR and/or SCR, BAT is to use an appropriate combination of the techniques given below.

 

Technique

Description

Applicability

(a)

Optimisation of the incineration process

See Section 2.1

Generally applicable.

(b)

Flue-gas recirculation

See Section 2.2

For existing plants, the applicability may be limited due to technical constraints (e.g. pollutant load in the flue-gas, incineration conditions).

(c)

Selective non-catalytic reduction (SNCR)

See Section 2.2

Generally applicable.

(d)

Selective catalytic reduction (SCR)

See Section 2.2

In the case of existing plants, the applicability may be limited by a lack of space.

(e)

Catalytic filter bags

See Section 2.2

Only applicable to plants fitted with a bag filter.

(f)

Optimisation of the SNCR/SCR design and operation

Optimisation of the reagent to NOX ratio over the cross-section of the furnace or duct, of the size of the reagent drops and of the temperature window in which the reagent is injected.

Only applicable where SNCR and/or SCR is used for the reduction of NOX emissions.

(g)

Wet scrubber

See Section 2.2.

Where a wet scrubber is used for acid gas abatement, and in particular with SNCR, unreacted ammonia is absorbed by the scrubbing liquor and, once stripped, can be recycled as SNCR or SCR reagent.

There may be applicability restrictions due to low water availability, e.g. in arid areas.


Table 6

BAT-associated emission levels (BAT-AELs) for channelled NOX and CO emissions to air from the incineration of waste and for channelled NH3 emissions to air from the use of SNCR and/or SCR

(mg/Nm3)

Parameter

BAT-AEL

Averaging period

New plant

Existing plant

NOX

50–120  (26)

50–150  (26)  (27)

Daily average

CO

10–50

10–50

NH3

2–10  (26)

2–10  (26)  (28)

The associated monitoring is in BAT 4.

1.5.2.4.   Emissions of organic compounds

BAT 30. In order to reduce channelled emissions to air of organic compounds including PCDD/F and PCBs from the incineration of waste, BAT is to use techniques (a), (b), (c), (d), and one or a combination of techniques (e) to (i) given below.

 

Technique

Description

Applicability

(a)

Optimisation of the incineration process

See Section 2.1.

Optimisation of incineration parameters to promote the oxidation of organic compounds including PCDD/F and PCBs present in the waste, and to prevent their and their precursors’ (re)formation.

Generally applicable.

(b)

Control of the waste feed

Knowledge and control of the combustion characteristics of the waste being fed into the furnace, to ensure optimal and, as far as possible, homogeneous and stable incineration conditions.

Not applicable to clinical waste or to municipal solid waste.

(c)

On-line and off-line boiler cleaning

Efficient cleaning of the boiler bundles to reduce the dust residence time and accumulation in the boiler, thus reducing PCDD/F formation in the boiler.

A combination of on-line and off-line boiler cleaning techniques is used.

Generally applicable.

(d)

Rapid flue-gas cooling

Rapid cooling of the flue-gas from temperatures above 400 °C to below 250 °C before dust abatement to prevent the de novo synthesis of PCDD/F.

This is achieved by appropriate design of the boiler and/or with the use of a quench system. The latter option limits the amount of energy that can be recovered from the flue-gas and is used in particular in the case of incinerating hazardous wastes with a high halogen content.

Generally applicable.

(e)

Dry sorbent injection

See Section 2.2.

Adsorption by injection of activated carbon or other reagents, generally combined with a bag filter where a reaction layer is created in the filter cake and the solids generated are removed.

Generally applicable.

(f)

Fixed- or moving-bed adsorption

See Section 2.2.

The applicability may be limited by the overall pressure drop associated with the FGC system. In the case of existing plants, the applicability may be limited by a lack of space.

(g)

SCR

See Section 2.2.

Where SCR is used for NOX abatement, the adequate catalyst surface of the SCR system also provides for the partial reduction of the emissions of PCDD/F and PCBs.

The technique is generally used in combination with technique (e), (f) or (i).

In the case of existing plants, the applicability may be limited by a lack of space.

(h)

Catalytic filter bags

See Section 2.2

Only applicable to plants fitted with a bag filter.

(i)

Carbon sorbent in a wet scrubber

PCDD/F and PCBs are adsorbed by carbon sorbent added to the wet scrubber, either in the scrubbing liquor or in the form of impregnated packing elements.

The technique is used for the removal of PCDD/F in general, and also to prevent and/or reduce the re-emission of PCDD/F accumulated in the scrubber (the so-called memory effect) occurring especially during shutdown and start-up periods.

Only applicable to plants fitted with a wet scrubber.


Table 7

BAT-associated emission levels (BAT-AELs) for channelled emissions to air of TVOC, PCDD/F and dioxin-like PCBs from the incineration of waste

Parameter

Unit

BAT-AEL

Averaging period

New plant

Existing plant

TVOC

mg/Nm3

< 3–10

< 3–10

Daily average

PCDD/F  (29)

ng I-TEQ/Nm3

< 0,01–0,04

< 0,01–0,06

Average over the sampling period

< 0,01–0,06

< 0,01–0,08

Long-term sampling period  (30)

PCDD/F + dioxin-like PCBs  (29)

ng WHO-TEQ/Nm3

< 0,01–0,06

< 0,01–0,08

Average over the sampling period

< 0,01–0,08

< 0,01–0,1

Long-term sampling period  (30)

The associated monitoring is in BAT 4.

1.5.2.5.   Emissions of mercury

BAT 31. In order to reduce channelled mercury emissions to air (including mercury emission peaks) from the incineration of waste, BAT is to use one or a combination of the techniques given below.

 

Technique

Description

Applicability

(a)

Wet scrubber

(low pH)

See Section 2.2.

A wet scrubber operated at a pH value around 1.

The mercury removal rate of the technique can be enhanced by adding reagents and/or adsorbents to the scrubbing liquor, e.g.:

oxidants such as hydrogen peroxide to transform elemental mercury to a water-soluble oxidised form;

sulphur compounds to form stable complexes or salts with mercury;

carbon sorbent to adsorb mercury, including elemental mercury.

When designed for a sufficiently high buffer capacity for mercury capture, the technique effectively prevents the occurrence of mercury emission peaks.

There may be applicability restrictions due to low water availability, e.g. in arid areas.

(b)

Dry sorbent injection

See Section 2.2.

Adsorption by injection of activated carbon or other reagents, generally combined with a bag filter where a reaction layer is created in the filter cake and the solids generated are removed.

Generally applicable.

(c)

Injection of special, highly reactive activated carbon

Injection of highly reactive activated carbon doped with sulphur or other reagents to enhance the reactivity with mercury.

Usually, the injection of this special activated carbon is not continuous but only takes place when a mercury peak is detected. For this purpose, the technique can be used in combination with the continuous monitoring of mercury in the raw flue-gas.

May not be applicable to plants dedicated to the incineration of sewage sludge.

(d)

Boiler bromine addition

Bromide added to the waste or injected into the furnace is converted at high temperatures to elemental bromine, which oxidises elemental mercury to the water-soluble and highly adsorbable HgBr2.

The technique is used in combination with a downstream abatement technique such as a wet scrubber or an activated carbon injection system.

Usually, the injection of bromide is not continuous but only takes place when a mercury peak is detected. For this purpose, the technique can be used in combination with the continuous monitoring of mercury in the raw flue-gas.

Generally applicable.

(e)

Fixed- or moving-bed adsorption

See Section 2.2.

When designed for a sufficiently high adsorption capacity, the technique effectively prevents the occurrence of mercury emission peaks.

The applicability may be limited by the overall pressure drop associated with the FGC system. In the case of existing plants, the applicability may be limited by a lack of space.


Table 8

BAT-associated emission levels (BAT-AELs) for channelled mercury emissions to air from the incineration of waste

(µg/Nm3)

Parameter

BAT-AEL (31)

Averaging period

New plant

Existing plant

Hg

< 5–20  (32)

< 5–20  (32)

Daily average or

average over the sampling period

1–10

1–10

Long-term sampling period

As an indication, the half-hourly average mercury emission levels will generally be:

< 15–40 µg/Nm3 for existing plants;

< 15–35 µg/Nm3 for new plants.

The associated monitoring is in BAT 4.

1.6.   Emissions to water

BAT 32. In order to prevent the contamination of uncontaminated water, to reduce emissions to water, and to increase resource efficiency, BAT is to segregate waste water streams and to treat them separately, depending on their characteristics.

Description

Waste water streams (e.g. surface run-off water, cooling water, waste water from flue-gas treatment and from bottom ash treatment, drainage water collected from the waste reception, handling and storage areas (see BAT 12(a)) are segregated to be treated separately based on their characteristics and on the combination of treatment techniques required. Uncontaminated water streams are segregated from waste water streams that require treatment.

When recovering hydrochloric acid and/or gypsum from the scrubber’s effluent, the waste waters arising from the different stages (acidic and alkaline) of the wet scrubbing system are treated separately.

Applicability

Generally applicable to new plants.

Applicable to existing plants within the constraints associated with the configuration of the water collection system.

BAT 33. In order to reduce water usage and to prevent or reduce the generation of waste water from the incineration plant, BAT is to use one or a combination of the techniques given below.

 

Technique

Description

Applicability

(a)

Waste-water-free FGC techniques

Use of FGC techniques that do not generate waste water (e.g. dry sorbent injection or semi-wet absorber, see Section 2.2).

May not be applicable to the incineration of hazardous waste with a high halogen content.

(b)

Injection of waste water from FGC

Waste water from FGC is injected into the hotter parts of the FGC system.

Only applicable to the incineration of municipal solid waste.

(c)

Water reuse/recycling

Residual aqueous streams are reused or recycled.

The degree of reuse/recycling is limited by the quality requirements of the process to which the water is directed.

Generally applicable.

(d)

Dry bottom ash handling

Dry, hot bottom ash falls from the grate onto a transport system and is cooled down by ambient air. No water is used in the process.

Only applicable to grate furnaces.

There may be technical restrictions that prevent retrofitting to existing incineration plants.

BAT 34. In order to reduce emissions to water from FGC and/or from the storage and treatment of slags and bottom ashes, BAT is to use an appropriate combination of the techniques given below, and to use secondary techniques as close as possible to the source in order to avoid dilution.

 

Technique

Typical pollutants targeted

Primary techniques

(a)

Optimisation of the incineration process (see BAT 14) and/or of the FGC system (e.g. SNCR/SCR, see BAT 29(f))

Organic compounds including PCDD/F, ammonia/ammonium

Secondary techniques (33)

Preliminary and primary treatment

(b)

Equalisation

All pollutants

(c)

Neutralisation

Acids, alkalis

(d)

Physical separation, e.g. screens, sieves, grit separators, primary settlement tanks

Gross solids, suspended solids

Physico-chemical treatment

(e)

Adsorption on activated carbon

Organic compounds including PCDD/F, mercury

(f)

Precipitation

Dissolved metals/metalloids, sulphate

(g)

Oxidation

Sulphide, sulphite, organic compounds

(h)

Ion exchange

Dissolved metals/metalloids

(i)

Stripping

Purgeable pollutants (e.g. ammonia/ammonium)

(j)

Reverse osmosis

Ammonia/ammonium, metals/metalloids, sulphate, chloride, organic compounds

Final solids removal

(k)

Coagulation and flocculation

Suspended solids, particulate-bound metals/metalloids

(l)

Sedimentation

(m)

Filtration

(n)

Flotation


Table 9

BAT-AELs for direct emissions to a receiving water body

Parameter

Process

Unit

BAT-AEL (34)

Total suspended solids (TSS)

FGC

Bottom ash treatment

mg/l

10–30

Total organic carbon (TOC)

FGC

Bottom ash treatment

15–40

Metals and metalloids

As

FGC

0,01–0,05

Cd

FGC

0,005–0,03

Cr

FGC

0,01–0,1

Cu

FGC

0,03–0,15

Hg

FGC

0,001–0,01

Ni

FGC

0,03–0,15

Pb

FGC

Bottom ash treatment

0,02–0,06

Sb

FGC

0,02–0,9

Tl

FGC

0,005–0,03

Zn

FGC

0,01–0,5

Ammonium-nitrogen (NH4-N)

Bottom ash treatment

10–30

Sulphate (SO4 2-)

Bottom ash treatment

400–1 000

PCDD/F

FGC

ng I-TEQ/l

0,01–0,05

The associated monitoring is in BAT 6.

Table 10

BAT-AELs for indirect emissions to a receiving water body

Parameter

Process

Unit

BAT-AEL  (35)  (36)

Metals and metalloids

As

FGC

mg/l

0,01–0,05

Cd

FGC

0,005–0,03

Cr

FGC

0,01–0,1

Cu

FGC

0,03–0,15

Hg

FGC

0,001–0,01

Ni

FGC

0,03–0,15

Pb

FGC

Bottom ash treatment

0,02–0,06

Sb

FGC

0,02–0,9

Tl

FGC

0,005–0,03

Zn

FGC

0,01–0,5

PCDD/F

FGC

ng I-TEQ/l

0,01–0,05

The associated monitoring is in BAT 6.

1.7.   Material efficiency

BAT 35. In order to increase resource efficiency, BAT is to handle and treat bottom ashes separately from FGC residues.

BAT 36. In order to increase resource efficiency for the treatment of slags and bottom ashes, BAT is to use an appropriate combination of the techniques given below based on a risk assessment depending on the hazardous properties of the slags and bottom ashes.

 

Technique

Description

Applicability

(a)

Screening and sieving

Oscillating screens, vibrating screens and rotary screens are used for an initial classification of the bottom ashes by size before further treatment.

Generally applicable.

(b)

Crushing

Mechanical treatment operations intended to prepare materials for the recovery of metals or for the subsequent use of those materials, e.g. in road and earthworks construction.

Generally applicable.

(c)

Aeraulic separation

Aeraulic separation is used to sort the light, unburnt fractions commingled in the bottom ashes by blowing off light fragments.

A vibrating table is used to transport the bottom ashes to a chute, where the material falls through an air stream that blows uncombusted light materials, such as wood, paper or plastic, onto a removal belt or into a container, so that they can be returned to incineration.

Generally applicable.

(d)

Recovery of ferrous and non-ferrous metals

Different techniques are used, including:

magnetic separation for ferrous metals;

eddy current separation for non-ferrous metals;

induction all-metal separation.

Generally applicable.

(e)

Ageing

The ageing process stabilises the mineral fraction of the bottom ashes by uptake of atmospheric CO2 (carbonation), draining of excess water and oxidation.

Bottom ashes, after the recovery of metals, are stored in the open air or in covered buildings for several weeks, generally on an impermeable floor allowing for drainage and run-off water to be collected for treatment.

The stockpiles may be wetted to optimise the moisture content to favour the leaching of salts and the carbonation process. The wetting of bottom ashes also helps prevent dust emissions.

Generally applicable.

(f)

Washing

The washing of bottom ashes enables the production of a material for recycling with minimal leachability of soluble substances (e.g. salts).

Generally applicable.

1.8.   Noise

BAT 37. In order to prevent or, where that is not practicable, to reduce noise emissions, BAT is to use one or a combination of the techniques given below.

Technique

Description

Applicability

(a)

Appropriate location of equipment and buildings

Noise levels can be reduced by increasing the distance between the emitter and the receiver and by using buildings as noise screens.

In the case of existing plants, the relocation of equipment may be restricted by a lack of space or by excessive costs.

(b)

Operational measures

These include:

improved inspection and maintenance of equipment;

closing of doors and windows of enclosed areas, if possible;

operation of equipment by experienced staff;

avoidance of noisy activities at night, if possible;

provisions for noise control during maintenance activities.

Generally applicable.

(c)

Low-noise equipment

This includes low-noise compressors, pumps and fans.

Generally applicable when existing equipment is replaced or new equipment is installed.

(d)

Noise attenuation

Noise propagation can be reduced by inserting obstacles between the emitter and the receiver. Appropriate obstacles include protection walls, embankments and buildings.

In the case of existing plants, the insertion of obstacles may be restricted by a lack of space.

(e)

Noise-control equipment/

infrastructure

This includes:

noise-reducers;

equipment insulation;

enclosure of noisy equipment;

soundproofing of buildings.

In the case of existing plants, the applicability may be limited by a lack of space.

2.   DESCRIPTIONS OF TECHNIQUES

2.1.   General techniques

Technique

Description

Advanced control system

The use of a computer-based automatic system to control the combustion efficiency and support the prevention and/or reduction of emissions. This also includes the use of high-performance monitoring of operating parameters and of emissions.

Optimisation of the incineration process

Optimisation of the waste feed rate and composition, of the temperature, and of the flow rates and points of injection of the primary and secondary combustion air to effectively oxidise the organic compounds while reducing the generation of NOX.

Optimisation of the design and operation of the furnace (e.g. flue-gas temperature and turbulence, flue-gas and waste residence time, oxygen level, waste agitation).

2.2.   Techniques to reduce emissions to air

Technique

Description

Bag filter

Bag or fabric filters are constructed from porous woven or felted fabric through which gases are passed to remove particles. The use of a bag filter requires the selection of a fabric suitable for the characteristics of the flue-gas and the maximum operating temperature.

Boiler sorbent injection

The injection of magnesium- or calcium-based absorbents at a high temperature in the boiler post-combustion area, to achieve partial abatement of acid gases. The technique is highly effective for the removal of SOX and HF, and provides additional benefits in terms of flattening emission peaks.

Catalytic filter bags

Filter bags are either impregnated with a catalyst or the catalyst is directly mixed with organic material in the production of the fibres used for the filter medium. Such filters can be used to reduce PCDD/F emissions as well as, in combination with a source of NH3, to reduce NOX emissions.

Direct desulphurisation

The addition of magnesium- or calcium-based absorbents to the bed of a fluidised bed furnace.

Dry sorbent injection

The injection and dispersion of sorbent in the form of a dry powder in the flue-gas stream. Alkaline sorbents (e.g. sodium bicarbonate, hydrated lime) are injected to react with acid gases (HCl, HF and SOX). Activated carbon is injected or co-injected to adsorb in particular PCDD/F and mercury. The resulting solids are removed, most often with a bag filter. The excess reactive agents may be recirculated to decrease their consumption, possibly after reactivation by maturation or steam injection (see BAT 28(b)).

Electrostatic precipitator

Electrostatic precipitators (ESPs) operate such that particles are charged and separated under the influence of an electrical field. Electrostatic precipitators are capable of operating under a wide range of conditions. The abatement efficiency may depend on the number of fields, residence time (size), and upstream particle removal devices. They generally include between two and five fields. Electrostatic precipitators can be of the dry or of the wet type depending on the technique used to collect the dust from the electrodes. Wet ESPs are typically used at the polishing stage to remove residual dust and droplets after wet scrubbing.

Fixed- or moving-bed adsorption

The flue-gas is passed through a fixed- or a moving-bed filter where an adsorbent (e.g. activated coke, activated lignite or a carbon-impregnated polymer) is used to adsorb pollutants.

Flue-gas recirculation

Recirculation of a part of the flue-gas to the furnace to replace a part of the fresh combustion air, with the dual effect of cooling the temperature and limiting the O2 content for nitrogen oxidation, thus limiting the NOX generation. It implies the supply of flue-gas from the furnace into the flame to reduce the oxygen content and therefore the temperature of the flame.

This technique also reduces the flue-gas energy losses. Energy savings are also achieved when the recirculated flue-gas is extracted before FGC, by reducing the gas flow though the FGC system and the size of the required FGC system.

Selective catalytic reduction (SCR)

Selective reduction of nitrogen oxides with ammonia or urea in the presence of a catalyst. The technique is based on the reduction of NOX to nitrogen in a catalytic bed by reaction with ammonia at an optimum operating temperature that is typically around 200–450 °C for the high-dust type and 170–250 °C for the tail-end type. In general, ammonia is injected as an aqueous solution; the ammonia source can also be anhydrous ammonia or a urea solution. Several layers of catalyst may be applied. A higher NOX reduction is achieved with the use of a larger catalyst surface, installed as one or more layers. ‘In-duct’ or ‘slip’ SCR combines SNCR with downstream SCR which reduces the ammonia slip from SNCR.

Selective non-catalytic reduction (SNCR)

Selective reduction of nitrogen oxides to nitrogen with ammonia or urea at high temperatures and without catalyst. The operating temperature window is maintained between 800 °C and 1 000 °C for optimal reaction.

The performance of the SNCR system can be increased by controlling the injection of the reagent from multiple lances with the support of a (fast-reacting) acoustic or infrared temperature measurement system so as to ensure that the reagent is injected in the optimum temperature zone at all times.

Semi-wet absorber

Also called semi-dry absorber. An alkaline aqueous solution or suspension (e.g. milk of lime) is added to the flue-gas stream to capture the acid gases. The water evaporates and the reaction products are dry. The resulting solids may be recirculated to reduce reagent consumption (see BAT 28(b)).

This technique includes a range of different designs, including flash-dry processes which consist of injecting water (providing for fast gas cooling) and reagent at the filter inlet.

Wet scrubber

Use of a liquid, typically water or an aqueous solution/suspension, to capture pollutants from the flue-gas by absorption, in particular acid gases, as well as other soluble compounds and solids.

To adsorb mercury and/or PCDD/F, carbon sorbent (as a slurry or as carbon-impregnated plastic packing) can be added to the wet scrubber.

Different types of scrubber designs are used, e.g. jet scrubbers, rotation scrubbers, Venturi scrubbers, spray scrubbers and packed tower scrubbers.

2.3.   Techniques to reduce emissions to water

Technique

Description

Adsorption on activated carbon

The removal of soluble substances (solutes) from the waste water by transferring them to the surface of solid, highly porous particles (the adsorbent). Activated carbon is typically used for the adsorption of organic compounds and mercury.

Precipitation

The conversion of dissolved pollutants into insoluble compounds by adding precipitants. The solid precipitates formed are subsequently separated by sedimentation, flotation or filtration. Typical chemicals used for metal precipitation are lime, dolomite, sodium hydroxide, sodium carbonate, sodium sulphide and organosulphides. Calcium salts (other than lime) are used to precipitate sulphate or fluoride.

Coagulation and flocculation

Coagulation and flocculation are used to separate suspended solids from waste water and are often carried out in successive steps. Coagulation is carried out by adding coagulants (e.g. ferric chloride) with charges opposite to those of the suspended solids. Flocculation is carried out by adding polymers, so that collisions of microfloc particles cause them to bond thereby producing larger flocs. The flocs formed are subsequently separated by sedimentation, air flotation or filtration.

Equalisation

Balancing of flows and pollutant loads by using tanks or other management techniques.

Filtration

The separation of solids from waste water by passing it through a porous medium. It includes different types of techniques, e.g. sand filtration, microfiltration and ultrafiltration.

Flotation

The separation of solid or liquid particles from waste water by attaching them to fine gas bubbles, usually air. The buoyant particles accumulate at the water surface and are collected with skimmers.

Ion exchange

The retention of ionic pollutants from waste water and their replacement by more acceptable ions using an ion exchange resin. The pollutants are temporarily retained and afterwards released into a regeneration or backwashing liquid.

Neutralisation

The adjustment of the pH of the waste water to a neutral value (approximately 7) by the addition of chemicals. Sodium hydroxide (NaOH) or calcium hydroxide (Ca(OH)2) is generally used to increase the pH whereas sulphuric acid (H2SO4), hydrochloric acid (HCl) or carbon dioxide (CO2) is used to decrease the pH. The precipitation of some substances may occur during neutralisation.

Oxidation

The conversion of pollutants by chemical oxidising agents to similar compounds that are less hazardous and/or easier to abate. In the case of waste water from the use of wet scrubbers, air may be used to oxidise sulphite (SO3 2-) to sulphate (SO4 2-).

Reverse osmosis

A membrane process in which a pressure difference applied between the compartments separated by the membrane causes water to flow from the more concentrated solution to the less concentrated one.

Sedimentation

The separation of suspended solids by gravitational settling.

Stripping

The removal of purgeable pollutants (e.g. ammonia) from waste water by contact with a high flow of a gas current in order to transfer them to the gas phase. The pollutants are subsequently recovered (e.g. by condensation) for further use or disposal. The removal efficiency may be enhanced by increasing the temperature or reducing the pressure.

2.4.   Management techniques

Technique

Description

Odour management plan

The odour management plan is part of the EMS (see BAT 1) and includes:

(a)

a protocol for conducting odour monitoring in accordance with EN standards (e.g. dynamic olfactometry according to EN 13725 to determine the odour concentration); it may be complemented by measurement/estimation of odour exposure (e.g. according to EN 16841-1 or EN 16841-2) or estimation of odour impact;

(b)

a protocol for response to identified odour incidents, e.g. complaints;

(c)

an odour prevention and reduction programme designed to identify the source(s), to characterise the contributions of the sources, and to implement prevention and/or reduction measures.

Noise management plan

The noise management plan is part of the EMS (see BAT 1) and includes:

(a)

a protocol for conducting noise monitoring;

(b)

a protocol for response to identified noise incidents, e.g. complaints;

(c)

a noise reduction programme designed to identify the source(s), to measure/estimate noise exposure, to characterise the contributions of the source(s) and to implement prevention and/or reduction measures.

Accident management plan

An accident management plan is part of the EMS (see BAT 1) and identifies hazards posed by the installation and the associated risks and defines measures to address these risks. It considers the inventory of pollutants present or likely to be present which could have environmental consequences if they escape. It can be drawn up using for example FMEA (Failure Mode and Effects Analysis) and/or FMECA (Failure Mode, Effects and Criticality Analysis).

The accident management plan includes the setting up and implementation of a fire prevention, detection and control plan, which is risk-based and includes the use of automatic fire detection and warning systems, and of manual and/or automatic fire intervention and control systems. The fire prevention, detection and control plan is relevant in particular for:

waste storage and pre-treatment areas;

furnace loading areas;

electrical control systems;

bag filters;

fixed adsorption beds.

The accident management plan also includes, in particular in the case of installations where hazardous wastes are received, personnel training programmes regarding:

explosion and fire prevention;

fire extinguishing;

knowledge of chemical risks (labelling, carcinogenic substances, toxicity, corrosion, fire).


(1)  Directive 2008/98/EC of the European Parliament and of the Council of 19 November 2008 on waste and repealing certain Directives (OJ L 312, 22.11.2008, p. 3).

(2)  Regulation (EC) No 850/2004 of the European Parliament and of the Council of 29 April 2004 on persistent organic pollutants and amending Directive 79/117/EEC (OJ L 158, 30.4.2004, p. 7).

(3)  For any parameter where, due to sampling or analytical limitations, 30-minute sampling/measurement and/or an average of three consecutive measurements is inappropriate, a more suitable procedure may be employed. For PCDD/F and dioxin-like PCBs, one sampling period of 6 to 8 hours is used in the case of short-term sampling.

(4)  Generic EN standards for continuous measurements are EN 15267-1, EN 15267-2, EN 15267-3 and EN 14181. EN standards for periodic measurements are given in the table or in the footnotes.

(5)  For periodic monitoring, the monitoring frequency does not apply where plant operation would be for the sole purpose of performing an emission measurement.

(6)  If continuous monitoring of N2O is applied, the generic EN standards for continuous measurements apply.

(7)  The continuous measurement of HF may be replaced by periodic measurements with a minimum frequency of once every six months if the HCl emission levels are proven to be sufficiently stable. No EN standard is available for the periodic measurement of HF.

(8)  For plants incinerating wastes with a proven low and stable mercury content (e.g. mono-streams of waste of a controlled composition), the continuous monitoring of emissions may be replaced by long-term sampling (no EN standard is available for long-term sampling of Hg) or periodic measurements with a minimum frequency of once every six months. In the latter case the relevant standard is EN 13211.

(9)  The monitoring only applies to the incineration of waste containing brominated flame retardants or to plants using BAT 31(d) with continuous injection of bromine.

(10)  The monitoring does not apply if the emission levels are proven to be sufficiently stable.

(11)  The monitoring does not apply where the emissions of dioxin-like PCBs are proven to be less than 0,01 ng WHO-TEQ/Nm3.

(12)  The monitoring frequency may be at least once every six months if the emissions are proven to be sufficiently stable.

(13)  The daily 24-hour flow-proportional composite sampling measurements may be substituted by daily spot sample measurements.

(14)  Either the loss on ignition or the total organic carbon is monitored.

(15)  Elemental carbon (e.g. determined according to DIN 19539) may be subtracted from the measurement result.

(16)  Either the BAT-AEPL for TOC content or the BAT-AEPL for the loss on ignition applies.

(17)  The lower end of the BAT-AEPL range can be achieved when using fluidised bed furnaces or rotary kilns operated in slagging mode.

(18)  The BAT-AEEL only applies where a heat recovery boiler is applicable.

(19)  The BAT-AEELs for gross electrical efficiency only apply to plants or parts of plants producing electricity using a condensing turbine.

(20)  The higher end of the BAT-AEEL range can be achieved when using BAT 20(f).

(21)  The BAT-AEELs for gross energy efficiency only apply to plants or parts of plants producing only heat or producing electricity using a back-pressure turbine and heat with the steam leaving the turbine.

(22)  A gross energy efficiency exceeding the higher end of the BAT-AEEL range (even above 100 %) can be achieved where a flue-gas condenser is used.

(23)  For the incineration of sewage sludge, the boiler efficiency is highly dependent on the water content of the sewage sludge as fed into the furnace.

(24)  For existing plants dedicated to the incineration of hazardous waste and for which a bag filter is not applicable, the higher end of the BAT-AEL range is 7 mg/Nm3.

(25)  The lower end of the BAT-AEL range can be achieved when using a wet scrubber; the higher end of the range may be associated with the use of dry sorbent injection.

(26)  The lower end of the BAT-AEL range can be achieved when using SCR. The lower end of the BAT-AEL range may not be achievable when incinerating waste with a high nitrogen content (e.g. residues from the production of organic nitrogen compounds).

(27)  The higher end of the BAT-AEL range is 180 mg/Nm3 where SCR is not applicable.

(28)  For existing plants fitted with SNCR without wet abatement techniques, the higher end of the BAT-AEL range is 15 mg/Nm3.

(29)  Either the BAT-AEL for PCDD/F or the BAT-AEL for PCDD/F + dioxin-like PCBs applies.

(30)  The BAT-AEL does not apply if the emission levels are proven to be sufficiently stable.

(31)  Either the BAT-AEL for daily average or average over the sampling period or the BAT-AEL for long-term sampling period applies. The BAT-AEL for long-term sampling may apply in the case of plants incinerating waste with a proven low and stable mercury content (e.g. mono-streams of waste of a controlled composition).

(32)  The lower end of the BAT-AEL ranges may be achieved when:

incinerating wastes with a proven low and stable mercury content (e.g. mono-streams of waste of a controlled composition), or

using specific techniques to prevent or reduce the occurrence of mercury peak emissions while incinerating non-hazardous waste.

The higher end of the BAT-AEL ranges may be associated with the use of dry sorbent injection.

(33)  The descriptions of the techniques are given in Section 2.3.

(34)  The averaging periods are defined in the General considerations.

(35)  The averaging periods are defined in the General considerations.

(36)  The BAT-AELs may not apply if the downstream waste water treatment plant is designed and equipped appropriately to abate the pollutants concerned, provided this does not lead to a higher level of pollution in the environment.


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